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Operators · VQE Hamiltonians and observables

Fermi–Hubbard Hamiltonian

Correlated lattice-fermion benchmark Hamiltonian. Representative form: H = -tΣ⟨ij⟩σ(c†ᵢσcⱼσ+h.c.) + UΣᵢnᵢ↑nᵢ↓.

Attested & literatureUpdated

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  • Primary sourceHubbard 1963, Proc. R. Soc. A 276
  • Read depthAbstract only — full text paywalled
  • Free routeNone found; pre-arXiv
  • Papers1

This record, used inside a worked example

This page says To use this record in VQE — here is a concrete, runnable instance of it.

VQE on a 2-qubit transverse-field Ising Hamiltonian

2 qubits, H = Z⊗Z + 0.5*(X⊗I + I⊗X), a stated toy Hamiltonian (not a molecule), minimised with a hardware-efficient ansatz.

q0q1RY(π/2)RY(5π/4)CXRY(0)RY(0)

Where it ends up

  • 1043%
  • 0143%
  • 007%
  • 117%

At these angles the ansatz's energy ⟨H⟩ reaches E0 = −√2, the Hamiltonian's exact ground energy; a real VQE run reaches these angles by repeating measure-the-energy then update-the-angles, not by a closed-form solution.

Open that example in Studio

This record is limited by what could be read, and says so. Hubbard's 1963 paper is the right primary source and its full text is paywalled, with no free preprint, author copy or open mirror found — it predates arXiv by nearly thirty years. The abstract was read directly from the publisher's page; everything below comes from it, and nothing is claimed from the body.

What the abstract states: that a main effect of correlation in dd- and ff-bands is to produce behaviour characteristic of the atomic or Heitler–London picture; that the paper introduces a simple approximate model for the interaction of electrons in narrow energy bands to study this; that Hartree–Fock is applied to that model and its results examined; that a Green function technique then yields an approximate solution to the correlation problem; that this solution reduces to the exact atomic solution in one limit and to the ordinary uncorrelated band picture in the opposite one; and that the condition for ferromagnetism of the solution is discussed, with a two-electron example given to clarify the physical meaning.

The limiting behaviour is the part that matters for this catalog, and it is in the abstract rather than needing the body: a model that interpolates between the atomic limit and the uncorrelated band limit is exactly a model with a tunable correlation strength, which is why the ratio U/tU/t became the standard dial and why this Hamiltonian is a benchmark rather than a curiosity.

What is deliberately not here. No equation number, no section reference, no statement about the paper's derivation or its notation, because the body was not read. The catalog's paper register records this source with reportsBasis: "abstract", so the gap is a fact the corpus knows about itself rather than an absence a reader has to infer. Closing it needs the PDF, which is an owner decision — he offered precisely that on ai-ops#44, and this record is the first concrete instance of the offer being needed.

References

Attested & literature
  • Peer-reviewed paper
Method
The DOI was opened in a browser after a curl request returned 403 — which on this publisher is a bot challenge and not evidence of a paywall. The rendered page gives the abstract and the sentence “You do not currently have access to this content.”
Result
Inconclusive on the paper's contents · abstract read and used; full text not read. The register records reportsBasis: "abstract" so the gap is countable rather than invisible.
Caveat
Indices, coefficients, basis conventions, mappings, and units are instance dependent and must be recorded in an executable experiment.
Electron correlations in narrow energy bands ↗
Kind
curated reference
Reviewed by
Leona Quantum curation pass
License
Citation metadata only; source publication terms apply
VQE operatorHamiltonianfermi–hubbard hamiltonianlattice fermionselectron correlation

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